catena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-μ-iodido]]
نویسنده
چکیده
The title complex, {(C(16)H(12)FN(2))[PbI(3)]}(n), consists of 1-[(2-fluoro-benzyl-idene)amino]-quinolinium cations and a polymeric PbI(3) (-) anion formed by face-sharing PbI(6) octa-hedra. These octa-hedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cation and one anionic [PbI(3)](-) fragment are observed in general positions. Polymeric chains are produced by the glide plane perpendicular to the a axis.
منابع مشابه
The one-dimensional organic–inorganic hybrid: catena-poly[bis[1-(3-ammoniopropyl)-1H-imidazolium] [[iodidoplumbate(II)]-tri-μ-iodido-plumbate(II)-tri-μ-iodido-[iodidoplumbate(II)]-di-μ-iodido]]
The organic-inorganic hybrid, {(C(6)H(13)N(3))(2)[Pb(3)I(10)]}(n), was obtained by the reaction of 1-(3-ammonio-prop-yl)imidazolium triiodide and PbI(2) at room temperature. The structure contains one-dimensional {[Pb(3)I(10)](4-)}(n) polymeric anions spreading parallel to [001], resulting from face-face-edge association of PbI(6) distorted octa-hedra. One of the Pb(II) cations is imposed at an...
متن کاملcatena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-diyl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]
The title compound, {(C(14)H(18)N(2))[Pb(2)I(6)]}(n), consists of discrete 1,1'-dimethyl-4,4'-(ethane-1,2-di-yl)dipyridinium cations and one-dimensional [Pb(2)I(6)](n) anions. The organic cation has an inversion center at the mid-point of the ethane C-C bond. In the anion, the Pb(II) atom is coordinated by six I atoms in a distorted octa-hedral geometry. The I atoms bridge the Pb(II) atoms into...
متن کاملCrystal structure of a new hybrid compound based on an iodidoplumbate(II) anionic motif
Crystals of the one-dimensional organic-inorganic lead iodide-based compound catena-poly[bis-(piperazine-1,4-diium) [[tetra-iodido-plumbate(II)]-μ-iodido] iodide monohydrate], (C4N2H12)2[PbI5]I·H2O, were obtained by slow evaporation at room temperature of a solution containing lead iodide and piperazine in a 1:2 molar ratio. Inorganic lead iodide chains, organic (C4N2H12)(2+) cations, water mol...
متن کاملcatena-Poly[[trans-bis(cyclohexane-1,2-diamine-κ2 N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido]
In the title compound, [Cd₂I₄(C₆H₁₄N₂)₂](n), there are two independent Cd(II) ions. One Cd(II) ion is coordinated in a slightly distorted octa-hedral coordination environment by four N atoms from two cyclo-hexane-1,2-diamine ligands and two iodido ligands. The other Cd(II) ion is coordinated by four iodido ligands in a slightly distorted tetra-hedral coordination environment. Two of the iodido ...
متن کاملcatena-Poly[[di-μ-iodido-dicopper(I)(Cu—Cu)]bis(μ-4,4′-di-3-pyridyl-2,2′-disulfanediyldipyrimidine)]
The title complex, [Cu(2)I(2)(C(18)H(12)N(6)S(2))(2)](n), contains a Cu(2)I(2) core with a Cu-Cu distance of 2.6935 (14) Å. The Cu(I) atom is coordinated by two bridging 4,4'-di-3-pyridyl-2,2'-disulfanediyldipyrimidine ligands and two bridging I atoms, forming a double chain.
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012